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关注：1
2013-05-23 12:21
求翻译：The analyses of the single crystal X-ray diffraction indicate that, in comparison to that of RhI(acac)(CO)(PPh3) with structural similarity to 1A–4A, the Rh P bonds in the ionic Rh(I)-complexes of 1A–4A are more consolidated along with the weakened Rh CO bonds due to the -backdonation interaction in Rh → P linkages, w是什么意思？ 待解决
 悬赏分：1
- 离问题结束还有
The analyses of the single crystal X-ray diffraction indicate that, in comparison to that of RhI(acac)(CO)(PPh3) with structural similarity to 1A–4A, the Rh P bonds in the ionic Rh(I)-complexes of 1A–4A are more consolidated along with the weakened Rh CO bonds due to the -backdonation interaction in Rh → P linkages, w
问题补充： |
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2013-05-23 12:21:38
单晶X射线衍射的分析表明，在比较该RHI （乙酰丙酮）（CO） （ PPH 3 ）与结构相似1A -4A ，在离子的Rh（ I）中所述的Rh P键的-complexes
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2013-05-23 12:23:18
正在翻译，请等待...
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2013-05-23 12:24:58
对单晶X-射线衍射的分析表明，与那RhI( acac比较)(CO)( PPh3) 以结构相似性对1A-4A， Rh P在离子Rh I(在)Rh → P连接结合- 1A-4A复合体与被减弱的Rh CO债券一起更被巩固由于 - backdonation互作用，促进CO ligand离解和随后CO插入为醋醛的迅速形成。
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2013-05-23 12:26:38
单晶 x 射线衍射分析表明与 RhI(acac)(CO)(PPh3) 与 1A — — 4A 的结构相似性，Rh P 在离子 Rh (I) 债券-1A — — 4A 配合更合并削弱的 Rh 公司债券-backdonation 相互作用在 Rh → P 的联系，方便的离解 CO 基配体，随后 CO 插入醛上迅速形成。
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2013-05-23 12:28:18
The analyses of the single crystal X-ray diffraction indicate that, in comparison to that of RhI(acac)(CO)(PPh3) with structural similarity to 1A-4A, the Rh P bonds in the ionic Rh(I)-complexes of 1A-4A are more consolidated along with the weakened Rh CO bonds due to the -backdonation interaction i
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