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  • 匿名
关注:1 2013-05-23 12:21

求翻译:The substrate scope for such deoxygenation of ketones were broadened using the monocation [(C6F5)3PF]+ and the dication [(SIMes)PFPh2]2+. In both cases, a variety of alkyl- and arylsubstituted ketones could be fully reduced to the alkane deoxygenation products. Interestingly, in contrast to arylketones, dialkyl ketones是什么意思?

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The substrate scope for such deoxygenation of ketones were broadened using the monocation [(C6F5)3PF]+ and the dication [(SIMes)PFPh2]2+. In both cases, a variety of alkyl- and arylsubstituted ketones could be fully reduced to the alkane deoxygenation products. Interestingly, in contrast to arylketones, dialkyl ketones
问题补充:

  • 匿名
2013-05-23 12:21:38
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  • 匿名
2013-05-23 12:23:18
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  • 匿名
2013-05-23 12:24:58
基体范围为酮的这样去氧使用monocation C6F5 ((变宽了)3PF) +和dication ((SIMes) PFPh2) 2+。 在两种情况下,各种各样烷基和arylsubstituted酮能充分地减少到烷去氧产品。 有趣的是,与arylketones对比, dialkyl酮能有选择性地是在硅酮面前一个等值hydrosilylated和随后deoxygenated与更多硅酮。
  • 匿名
2013-05-23 12:26:38
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  • 匿名
2013-05-23 12:28:18
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